88733-72-6Relevant articles and documents
ACYLATION REACTION OF HYDROXYL GROUP
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Page/Page column 15-16, (2010/07/03)
Disclosed is a selective ester production process of an alcoholic hydroxyl group, which proceeds under chemically mild conditions, while having adequate environmental suitability, operability and economical efficiency. Specifically disclosed is a process for producing an ester compound, which is characterized in that an alcohol and a carboxylic acid ester compound are reacted in the presence of a compound containing zinc element, thereby selectively acylating a hydroxyl group of the alcohol.
ANOMALOUS ORIENTATION EFFECTS DURING BENZOYLOXYLATIONS BY "SILVER BROMIDE DIBENZOATE"
Bryce-Smith, Derek,Isaacs, Neil S.,Tumi, Seddeg O.
, p. 1471 - 1472 (2007/10/02)
The solid complex formed from bromine and silver benzoate reacts with both arenes and alkenes to form aryl and alkyl benzoates, respectively.Highly unusual substituent effects are observed in the benzoyloxylations of arenes.Electron-withdrawing groups (e.g. -NO2, -CN,-CO-) on the aromatic ring facilitate reaction though directing the attacking reagent exclusively to the meta position.In alkanes, tertiary positions are most prone to attack.