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ALIPHATIC AND AROMATIC 5-NITRO-2-FURYLAMINES AND AROMATIC 5-NITROFURFURYL ETHERS
Mocelo, Raul,Kovac, Jaroslav
, p. 2682 - 2692 (2007/10/02)
Tertiary 5-nitrofurylamines were prepared by a nucleophilic substitution of 5-nitro-2-furfuryl bromide (I) with aliphatic secondary amines.According to reaction conditions N-(5-nitro-2-furfuryl)-X-phenylamines or their mixture with N,N-di(5-nitro-2-furfuryl)-X-phenylamines were obtained from the reaction of I with substituted primary aromatic amines.Compound I gave with 2-aminophenol a mixture of O- and N-mono- and disubstituted derivatives, and with ethyl salicylate ethyl 2-(5-nitro-2-furfuryloxy)benzoate.