88811-66-9Relevant articles and documents
Thermally Induced Rearrangement of (Acyloxymethyl)diorganylsilanes
Tacke, Reinhold,Lange, Hartwig
, p. 3685 - 3691 (2007/10/02)
The (acyloxymethyl)diorganylsilanes R1R2Si(H)CH2OC(O)R3 (2a-d) rearrange to the corresponding acyloxy(methyl)diorganylsilanes R1R2Si(CH3)OC(O)R3 (3a-d).This reaction is formally equivalent to an exchange of the hydrogen bound to silicon and acyloxy group bound to carbon.The 1,2-hydrogen shift could be shown experimentally to be an intramolecular process.