890-50-6

Basic information

• Product Name: N-Phenylnaphthalene-1-(methanimine)
• Synonyms: N-(1-Naphtylmethylene)aniline;N-Phenyl(1-naphtyl)methanimine;N-Phenyl-1-naphthalenemethanimine;N-Phenylnaphthalene-1-(methanimine);N-Phenylnaphthalene-1-methanimine;N-Phenyl-α-(1-naphtyl)methanimine;1-naphthalen-1-yl-N-phenylmethanimine
• CAS NO: 890-50-6
• Molecular Formula: C₁₇H₁₃N
• Molecular Weight: 231.29182
• Mol File: 890-50-6.mol
• Article Data: 35

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Phenylnaphthalene-1-(methanimine)(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenylnaphthalene-1-(methanimine)(890-50-6)
• EPA Substance Registry System: N-Phenylnaphthalene-1-(methanimine)(890-50-6)

Safety Data

• Hazardous Substances Data: 890-50-6(Hazardous Substances Data)

Upstream product

• 66-77-3 1-naphthaldehyde 
• 62-53-3 aniline 
• 26153-26-4 1-naphthylglyoxylic acid 
• 91-20-3 naphthalene 
• 33656-65-4 ethyl 2-(1-naphthyl)-2-oxoacetate 
• 4780-79-4 1-naphthalene methanol 
• 98-95-3 nitrobenzene 
• 64-10-8 phenyl carbamate 

Downstream Products

• 114999-37-0 3-anilino-3-[1]naphthyl-2-phenyl-propionic acid 
• 13026-12-5 (E)-3-(naphthalen-1-yl)acrylic acid 
• 16178-01-1 2-biphenyl-4-yl-5-methyl-6-(trans-2-naphthalen-1-yl-vinyl)-benzooxazole 
• 16178-24-8 4,5-bis-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-2-phenyl-oxazole 
• 16219-27-5 2-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-5-phenyl-oxazole 
• 23798-61-0 trans-1-<4-Methoxy-phenyl>-2-<4-(-2-naphthyl-(1)-aethenyl)-phenyl>-acetylen 
• 23833-49-0 trans-1,2-Bis-<4-(2-naphthyl-(1)-ethenyl)-phenyl>-acetylen 
• 16157-27-0 2-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-5-phenyl-[1,3,4]oxadiazole 
• 23798-79-0 trans-1-Phenyl-4-(4-(2-naphthyl-⁽¹⁾-ethenyl)-phenyl)-butadien 
• 23798-54-1 trans-1-Phenyl-2-(4-(2-naphthyl-⁽¹⁾-ethenyl)-phenyl)-acetylen 
• 23798-74-5 trans-1-p-Biphenyl-2-<4-(2-naphthyl-1-ethenyl)-phenyl>-acetylen 
• 16178-19-1 2-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-4,5-diphenyl-oxazole 
• 16157-28-1 2-(4-tert-butyl-phenyl)-5-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-[1,3,4]oxadiazole 
• 16143-25-2 2-[4-(trans-2-naphthalen-1-yl-vinyl)-phenyl]-6-phenyl-benzooxazole 

Relevant articles and documents

Visible-Light-Induced Cycloaddition of α-Ketoacylsilanes with Imines: Facile Access to β-Lactams

We report the synthesis of β-lactams from α-ketoacylsilanes and imines, which proceeds via a formal [2+2] photochemical cycloaddition with in situ generation of siloxyketene. This mild and operationally simple reaction proceeds in an atom-economic fashion with broad substrate scope, including aldimines, ketimines, hydrazones, and fused nitrogen heterocycles, affording a variety of important β-lactams with satisfactory diastereoselectivities in most cases. This reaction also features good functional-group tolerance, facile scalability and product diversification. Experimental and computational studies suggest that α-ketoacylsilanes can serve as photochemical precursors by engaging in a 1,3 silicon shift to the distal carbonyl group.

Rhodium catalyzed multicomponent dehydrogenative annulation: one-step construction of isoindole derivatives

A strategy for one-pot synthesis of isoindoles is describedviaa catalytic multicomponent dehydrogenative annulation of diarylimines, vinyl ketones and simple amines. In the presence of a rhodium catalyst and Cu oxidant, four C-H and two N-H bonds are activated along with the formation of one new C-C and two new C-N bonds, leading to a series of isoindole derivatives in good to very high isolated yields.

Catalyst- And solvent-free efficient access to: N -alkylated amines via reductive amination using HBpin

A sustainable approach which works under catalyst- and solvent-free conditions for the synthesis of structurally diverse secondary amines has been uncovered. This one-pot protocol works efficiently at room temperature and is compatible with a wide range of sterically and electronically diverse aldehydes and primary amines. Notably, this simple process offers scalability, excellent functional group tolerance, chemoselectivity, and is also effective at the synthesis of biologically relevant molecules. This journal is