890002-97-8

Basic information

• Product Name: [1-(2-chlorophenyl)cycloprop-2-en-1-yl]methanol
• Synonyms: [1-(2-chlorophenyl)cycloprop-2-en-1-yl]methanol
• CAS NO: 890002-97-8
• Molecular Weight: 180.634
• Mol File: 890002-97-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [1-(2-chlorophenyl)cycloprop-2-en-1-yl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(2-chlorophenyl)cycloprop-2-en-1-yl]methanol(890002-97-8)
• EPA Substance Registry System: [1-(2-chlorophenyl)cycloprop-2-en-1-yl]methanol(890002-97-8)

Safety Data

• Hazardous Substances Data: 890002-97-8(Hazardous Substances Data)

Upstream product

• 264882-00-0 methyl 2-(2-chlorophenyl)-2-diazoacetate 
• 890002-82-1 methyl 1-(2-chlorophenyl)-2-(trimethylsilyl)cycloprop-2-ene-1-carboxylate 

Relevant articles and documents

An expedient synthesis of highly functionalized 1,3-dienes by employing cyclopropenes asC4units

An efficient method has been described to synthesize dicarbonyl functionalized 1,3-dienes by cleaving the CC bond of enaminones with cyclopropenes in the presence of a rhodium catalyst. The acetate-substituted cyclopropenes are judiciously chosen as standardC4units of 1,3-diene precursors. The reactions are believed to undergo a unique cutting and insertion process, involving a CC bond cleavage of the enaminone and insertion of a newC(sp2) source with the formation of two C-C single bonds. A broad range of substrates can be used to synthesize the corresponding 1,3-dienes under very mild reaction conditions, including low catalyst-loading, ambient temperature, and a neutral reaction solvent.