890016-48-5Relevant articles and documents
Photoredox catalyzed dealkylative aromatic halogen substitution with tertiary amines
Dilman, Alexander D.,Frumkin, Alexander E.,Levin, Vitalij V.,Lipilin, Dmitry L.,Tyurin, Alexey Yu.
, (2021/06/18)
A reaction of aromatic halides bearing electron-withdrawing groups with tertiary amines in the presence of an iridium catalyst under blue light irradiation is described. Products of the aromatic substitution of the halide by the dialkylamino fragment are
Copper-catalyzed direct amination of polyfluoroarenes and azoles with hydroxylamines and its application to the synthesis of 3-aminobenzoheteroles
Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
experimental part, p. 1792 - 1797 (2012/07/28)
A copper-catalyzed electrophilic, umpolung amination strategy for the direct C-H amination of polyfluoroarenes and 1,3-azoles has been developed. The copper-based amination reaction is robust and can be easily scaled up on a gram scale. Its application to
