89368-01-4

Basic information

• Product Name: Oxirane, (2-phenylethenyl)-, (E)-
• CAS NO: 89368-01-4
• Molecular Formula: C10H10O
• Molecular Weight: 146.189
• Mol File: 89368-01-4.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: Oxirane, (2-phenylethenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, (2-phenylethenyl)-, (E)-(89368-01-4)
• EPA Substance Registry System: Oxirane, (2-phenylethenyl)-, (E)-(89368-01-4)

Safety Data

• Hazardous Substances Data: 89368-01-4(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 6814-64-8 methylenedimethyl sulfurane 
• 1030268-21-3 trimethylsulfonium iodide 
• 2181-44-4 trimethylsulfonium methylsulfate 
• 104-55-2 3-phenyl-propenal 
• 74-95-3 1,1-dibromomethane 
• 75-11-6 diiodomethane 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 93-59-4 Perbenzoic acid 
• 1515-78-2 buta-1,3-dien-1-ylbenzene 
• 105885-67-4 (+/-)-(3E)-1-chloro-4-phenyl-but-3-en-2-ol 
• 333-27-7 methyl trifluoromethanesulfonate 
• 122-78-1 phenylacetaldehyde 
• 6052-66-0 1-phenyl-3-buten-2-ol 

Downstream Products

• 114275-02-4 4-phenyl-2-(trimethylsilylethynyl)-3-buten-1-ol 
• 57662-64-3 2-((E)-Styryl)-thiirane 
• 124558-53-8 3,3-Dichloro-4-phenyl-2,3,4,7-tetrahydrooxepin-2-one 
• 123614-03-9 (E)-2,4-diphenylbut-3-en-1-ol 
• 114467-66-2 (E)-4-Phenyl-2,5-hexadien-1-ol 
• 83413-27-8 (E)-4-phenyl-2-vinylbut-3-en-1-ol 
• 205641-03-8 (E)-2-Chloro-4-phenylbut-3-en-1-ol 
• 325459-04-9 (±)-(E)-1-phenylhepta-1,6-dien-4-ol 
• 937-58-6 (3E)-4-phenyl-3-buten-1-ol 
• 1126-76-7 1,2-Epoxy-4-phenylbutane 
• 3360-41-6 4-phenyl-butan-1-ol 
• 1204-60-0 biphenyl-3-carbaldehyde 
• 1896-62-4 (E)-benzalacetone 
• 1610376-79-8 (E)-S-(1-hydroxy-4-phenylbut-3-en-2-yl) O,O-diethyl phosphorodithioate 

Relevant articles and documents

Mechanochemical Synthesis of 1,2-Diketoindolizine Derivatives from Indolizines and Epoxides Using Piezoelectric Materials

A simple and efficient mechanochemical-induced approach for the synthesis of 1,2-diketoindolizine derivatives has been developed. BaTiO3 was used as the piezoelectric material in this transformation. This method features no usage of solvent, simple experimental operation, scalable potential, and high conversion efficiency, which make it attractive and practical.

Nucleophilic Organic Base DABCO-Mediated Chemospecific Meinwald Rearrangement of Terminal Epoxides into Methyl Ketones

Nucleophilic organic base DABCO (1,4-diazabicyclo[2.2.2]octane)-mediated Meinwald rearrangement of various epoxides was investigated. 2-Aryl-, alkenyl-, and alkynylepoxides generate the corresponding methyl ketones chemospecifically in good to excellent yields. The current DABCO-mediated Meinwald rearrangement of epoxides features readily accessible starting materials, a wide substrate scope, a transition-metal- and acid-free environment, and chemospecificity in the isomerization of epoxides.

Chemo-, regio-, and stereo-selective perfluoroalkylations by a Grignard complex with zirconocene

The synthesis of highly reactive perfluoroalkyl Grignard reagents with early transition metal zirconocene complexes and their new types of highly chemo-, regio-, and stereo-selective perfluoroalkylation reactions are reported with epoxides in particular. The zirconocene complex is advantageous in activating the perfluoroalkyl Grignard species. The zirconocene·Grignard complexes were clarified by DOSY. Both 1H and 19F DOSY analyses show that the addition of MAO and dioxane to the mixture of RFMgCl and Cp2ZrCl2 connects Cp2Zr and RFMg to generate the zirconocene/perfluoroalkyl-Grignard/dioxane complex.