89393-52-2

Basic information

• Product Name: 1-Pyrrolidinamine, 2-(methoxymethyl)-N-(1-methylhexylidene)-, (S)-
• CAS NO: 89393-52-2
• Molecular Formula: C13H26N2O
• Molecular Weight: 226.362
• Mol File: 89393-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinamine, 2-(methoxymethyl)-N-(1-methylhexylidene)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinamine, 2-(methoxymethyl)-N-(1-methylhexylidene)-, (S)-(89393-52-2)
• EPA Substance Registry System: 1-Pyrrolidinamine, 2-(methoxymethyl)-N-(1-methylhexylidene)-, (S)-(89393-52-2)

Safety Data

• Hazardous Substances Data: 89393-52-2(Hazardous Substances Data)

Upstream product

• 110-43-0 n-pentyl methyl ketone 
• 59983-39-0 (S)-1-amino-2-(methoxymethyl)pyrrolidine 

Downstream Products

• 89393-77-1 (R)-5-Oxo-3-phenyl-decanoic acid methyl ester 
• 89393-65-7 (R)-5-[(E)-(S)-2-Methoxymethyl-pyrrolidin-1-ylimino]-3-phenyl-decanoic acid methyl ester 

Relevant articles and documents

ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED δ-KETOESTERS VIA MICHAEL-ADDITIONS OF SAMP/RAMP-HYDRAZONES TO α,β-UNSATURATED ESTERS, VIRTUALLY COMPLETE 1.6-ASYMMETRIC INDUCTION

A simple and efficient 3-step asymmetric synthesis of β-substituted δ-ketoesters 3 in 45-62percent overall chemical yield and >=96-ca.100percent ee is described.The key step is an asymmetric Michael-addition of lithiated methylketone-SAMP- or RAMP-hydrazones to α,β-unsaturated esters 2 with virtually complete 1.6-asymmetric induction.