894810-82-3

Basic information

• Product Name: N-allyl-N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester
• Synonyms: N-allyl-N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester
• CAS NO: 894810-82-3
• Molecular Weight: 379.864
• Mol File: 894810-82-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-allyl-N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester(894810-82-3)
• EPA Substance Registry System: N-allyl-N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester(894810-82-3)

Safety Data

• Hazardous Substances Data: 894810-82-3(Hazardous Substances Data)

Upstream product

• 77820-58-7 methyl 3-chloroanthranilate 
• 6388-47-2 2-amino-3-chlorobenzoic acid 
• 106-95-6 allyl bromide 
• 247237-41-8 N-p-toluenesulfonyl-3-chloroanthranilic acid methyl ester 

Downstream Products

• 894810-83-4 N-allyl-N-p-toluenesulfonyl-2-chloro-6-(hydroxymethyl)aniline 
• 894810-84-5 N-allyl-N-p-toluenesulfonyl-2-chloro-6-formylaniline 
• 894810-43-6 N-allyl-N-(2-chloro-6-vinyl-phenyl)-4-methyl-benzenesulfonamide 
• 143262-07-1 7-chloro-N-p-tolylsulfonylindole 

Relevant articles and documents

Development of isomerization and cycloisomerization with use of a ruthenium hydride with N-heterocyclic carbene and its application to the synthesis of heterocycles

A pure ruthenium hydride complex with N-heterocyclic carbene (NHC) ligand was efficiently generated from the reaction of a second-generation Grubbs ruthenium catalyst with vinyloxytrimethylsilane and unambiguously characterized. This ruthenium hydride complex showed high catalytic activity for the selective isomerization of terminal olefin and for the cycloisomerization of 1,6-dienes. These reactions of N-allyl-o-vinylaniline lead to novel synthetic methods for heterocycles such as indoles and 3-methylene-2,3-dihydroindoles, which are useful synthons for bioactive natural products. These procedures address an important issue in diversity-oriented synthesis.