89525-11-1

Basic information

• Product Name: Acetic acid, (diethoxyphosphinyl)[[(phenylmethoxy)carbonyl]amino]-
• CAS NO: 89525-11-1
• Molecular Formula: C14H20NO7P
• Molecular Weight: 345.289
• Mol File: 89525-11-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetic acid, (diethoxyphosphinyl)[[(phenylmethoxy)carbonyl]amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, (diethoxyphosphinyl)[[(phenylmethoxy)carbonyl]amino]-(89525-11-1)
• EPA Substance Registry System: Acetic acid, (diethoxyphosphinyl)[[(phenylmethoxy)carbonyl]amino]-(89525-11-1)

Safety Data

• Hazardous Substances Data: 89525-11-1(Hazardous Substances Data)

Upstream product

• 79002-45-2 N-benzyloxycarbonyl-glycine 
• 127357-37-3 methyl 2-(benzyloxycarbonylamino)-2-methoxyacetate 
• 64356-76-9 N-benzyloxycarbonyl α-chloro glycine methyl ester 
• 83026-99-7 2-Benzyloxycarbonylamino-2-diethyloxyphosphoryl-essigsaeure-ethylester 
• 114684-69-4 methyl 2-(benzyloxycarbonylamino)-2-(diethyloxyphosphoryl)acetate 
• 621-84-1 O-benzyl carbamate 

Downstream Products

• 917603-66-8 (2R,3E)-2-benzyl-2-benzyloxycarbonylaminododec-3-enoic acid (-)-8-phenylmenthyl ester 
• 917603-61-3 (Z)-2-benzyloxycarbonylaminododec-2-enoic acid (-)-8-phenylmenthyl ester 
• 917603-63-5 (Z)-2-benzyloxycarbonylamino-5-phenylpent-2-enoic acid (-)-8-phenylmenthyl ester 
• 917603-60-2 benzyloxycarbonylamino(diethoxyphosphoryl)acetic acid (-)-8-phenylmenthyl ester 
• 185759-88-0 [2-Benzyloxycarbonylamino-2-(diethoxy-phosphoryl)-acetylamino]-acetic acid tert-butyl ester 
• 89525-06-4 t-Butyl 2-(benzyloxycarbonylamino)-2-(diethoxyphosphinyl)-acetate 

Relevant articles and documents

Efficient asymmetric synthesis of quaternary (E)-vinylglycines by deconjugative alkylation of dehydroamino acids

A two-step protocol for the asymmetric synthesis of protected quaternary (E)-vinylglycines from simple aldehydes is reported. The key step is a regiocontrolled deconjugative asymmetric alkylation of dehydroamino acids, giving the targets as single geometric isomers with high diastereoselectivity (92-96% de). The products can be converted to valuable quaternary β-amino alcohols by chemoselective reduction.

Phosphono analogues of glutathione as new inhibitors of glutathione S-transferases

Phosphono-analogues of glutathione containing the O=P(OR)2 moiety in place of the cysteinyl residue CH2SH 1a-1d were prepared by solution phase peptide synthesis. Benzyl, benzyloxycarbonyl, and tert-butyl protecting groups were used

Amino Acids and Peptides; XLIII. Dehydroamino Acids; XVIII. Synthesis of Dehydroamino Acids and Amino Acids from N-Acyl-2-(dialkyloxyphosphinyl)-glycin Esters; II

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