89525-20-2

Basic information

• Product Name: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis[2-[[(phenylmethoxy)carbonyl]amino]-, dimethyl ester, (Z,Z)-
• CAS NO: 89525-20-2
• Molecular Formula: C30H28N2O8
• Molecular Weight: 544.561
• Mol File: 89525-20-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis[2-[[(phenylmethoxy)carbonyl]amino]-, dimethyl ester, (Z,Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis[2-[[(phenylmethoxy)carbonyl]amino]-, dimethyl ester, (Z,Z)-(89525-20-2)
• EPA Substance Registry System: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis[2-[[(phenylmethoxy)carbonyl]amino]-, dimethyl ester, (Z,Z)-(89525-20-2)

Safety Data

• Hazardous Substances Data: 89525-20-2(Hazardous Substances Data)

Upstream product

• 127357-37-3 methyl 2-(benzyloxycarbonylamino)-2-methoxyacetate 
• 626-19-7 Isophthalaldehyde 
• 100945-15-1 N-(benzyloxycarbonyl)phosphonoglycine trimethyl ester 

Downstream Products

• 904704-08-1 3-[3-(2-methoxycarbonyl-2-prop-2-ynyloxycarbonylamino-ethyl)-phenyl]-2-prop-2-ynyloxycarbonylaminopropionic acid methyl ester 
• 904704-07-0 3-[3-(2-methoxycarbonyl-2-propionylamino-ethyl)-phenyl]-2-propionylamino-propionic acid methyl ester 

Relevant articles and documents

Enantioselective synthesis of diamino dicarboxylic acids

The preparation of alkyl diamino dicarboxylic acids with high optical purity (100% ee, >98.5% de) and high yields based on asymmetric catalytic hydrogenation is described. The required prochiral precursors are prepared from dialdehydes and Z-, Boc-, and acetyl-protected phosphonoglycines. Aqueous solutions of glyoxal, succinic dialdehyde, and glutaric dialdehyde were used to prepare the diunsaturated precursors for 2,5-diaminoadipic acid (DAA), 2,7-diaminosuberic acid (DAS), and 2,8-diaminoazelaic acid (DAZ). Z- Protected dimethyl esters of DAA, DAS, and DAZ were obtained by hydrogenation of the corresponding prochiral starting materials with [(COD)Rh(S,S)- EtDuPHOS]OTf.