898769-06-7

Basic information

• Product Name: 3-BROMOPHENYL CYCLOHEXYL KETONE
• Synonyms: 3-BROMOPHENYL CYCLOHEXYL KETONE
• CAS NO: 898769-06-7
• Molecular Formula: C₁₃H₁₅BrO
• Molecular Weight: 267.16
• Mol File: 898769-06-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 351.6°C at 760 mmHg
• Flash Point: 64°C
• Appearance: /
• Density: 1.338g/cm³
• Vapor Pressure: 4.07E-05mmHg at 25°C
• Refractive Index: 1.564
• CAS DataBase Reference: 3-BROMOPHENYL CYCLOHEXYL KETONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMOPHENYL CYCLOHEXYL KETONE(898769-06-7)
• EPA Substance Registry System: 3-BROMOPHENYL CYCLOHEXYL KETONE(898769-06-7)

Safety Data

• Hazardous Substances Data: 898769-06-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H15BrO/c14-12-8-4-7-11(9-12)13(15)10-5-2-1-3-6-10/h4,7-10H,1-3,5-6H2

Upstream product

• 3132-99-8 m-bromobenzoic aldehyde 
• 110-82-7 cyclohexane 
• 108-85-0 1-bromocyclohexane 
• 35306-75-3 3-bromobenzoic acid isopropylamide 
• 6815-55-0 1-(cyclohexylidenemethyl)pyrrolidine 

Downstream Products

• 1258203-15-4 C₁₄H₁₈BrN₃S 
• 1370549-36-2 tert-butyl 2-(3-(cyclohexanecarbonyl)phenyl)allylcarbamate 
• 1370549-46-4 (E)-N,N-bis(tert-butoxycarbonyl)-3-(3-(cyclohexanecarbonyl)phenyl)prop-2-en-1-amine 
• 1372806-14-8 C₁₆H₁₉BrN₂O₂ 
• 1372806-29-5 C₁₆H₁₉BrN₂OS 
• 1049641-18-0 C₁₆H₂₀BrN₃O 
• 1049650-21-6 C₂₂H₂₄ClN₃O 
• 1372805-99-6 C₁₅H₁₇BrN₂O₂ 

Relevant articles and documents

Cross-Coupling of Secondary Amides with Tertiary Amides: The Use of Tertiary Amides as Surrogates of Alkyl Carbanions for Ketone Synthesis

In recent years, exciting progress has been made in the field of direct transformation of amides, nevertheless, the condensation between two amides remains rare and restricted to homo-coupling reactions. Herein, we report the cross-coupling of secondary amides with tertiary amides, which provides a synthesis of ketones under mild conditions, and features the use of tertiary amides as surrogates of alkyl carbanions. The method relies on the coupling of enamines, generated from tertiary amides by catalytic partial reduction of tertiary amides with Vaska's catalyst, with nitrilium ions, formed in situ from secondary amides via activation with trifluoromethanesulfonic anhydride, and on the subsequent deformylation.

A ketone the synthetic method of the compound of (by machine translation)

The invention discloses a method for the synthesis of ketone compound, the aldehyde compound and cyclanes mixed or dissolved in organic solvent, in the microwave radiation and presence of radical initiator under the condition of the 140 [...] 180 °C reaction to obtain the target product ketone compound, in the synthesis method of the reaction equation: , Wherein R 1 is phenyl or substituted phenyl, substituted phenyl benzene ring substituted the base is the fluorine, chloro, bromo, methyl, methoxy, trifluoromethyl or hydroxy in one or more of, the position of the substituent on the benzene ring is ortho, meta or para position, as n the 1 [...] 4 integer between the, free-radical initiator is benzoyl peroxide, di-tert-butyl peroxide, or cumyl peroxide, organic solvent as the alkane or benzene. The invention discloses method for the synthesis of the raw material is cheap and easy to obtain, good atom economy, wide range of the application of substrates, and the like, is suitable for industrial production. (by machine translation)