89998-62-9Relevant articles and documents
Thermal -Sigmatropic Hydrogen Shifts: Stereochemistry, Kinetics, Isotope Effects, and ?-Facial Selectivity
Hoeger, Carl A.,Johnston, Allen D.,Okamura, William H.
, p. 4690 - 4698 (2007/10/02)
The antarafacial stereochemistry of the thermal -sigmatropic hydrogen shift has been demonstrated.The substrates studied include the epimeric cis-isotachysterol analogues 1 and 4 and their stereospecifically 15α-deuterium-labelled derivatives 7 and 1