900150-11-0

Basic information

• Product Name: N,N-dimethyl-N,N-bis(2-nitrophenyl)benzene-1,3-dicarboxamide
• Synonyms: N,N-dimethyl-N,N-bis(2-nitrophenyl)benzene-1,3-dicarboxamide
• CAS NO: 900150-11-0
• Molecular Weight: 464.434
• Mol File: 900150-11-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-dimethyl-N,N-bis(2-nitrophenyl)benzene-1,3-dicarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-N,N-bis(2-nitrophenyl)benzene-1,3-dicarboxamide(900150-11-0)
• EPA Substance Registry System: N,N-dimethyl-N,N-bis(2-nitrophenyl)benzene-1,3-dicarboxamide(900150-11-0)

Safety Data

• Hazardous Substances Data: 900150-11-0(Hazardous Substances Data)

Upstream product

• 1951-38-8 2-methoxyisophthalic acid 
• 576-26-1 2.6-dimethylphenol 
• 612-28-2 2-nitro-N-methylaniline 
• 2390-40-1 anisole-2,6-dicarboxylic acid bis acid chloride 
• 1004-66-6 2-methoxy-1,3-dimethylbenzene 

Relevant articles and documents

A minimalist approach to C-H activation by copper

The complex [Cu2(1)2]2+ (1=1,3-bis(1-methyl-1H-benzimidazol-2-yl)benzene) undergoes slow oxidation by dioxygen in DMF solution to give the hydroxylated product [Cu 2(2-H)2]2+ (2=2,6-bis(1-methyl-1H-benzimidazol- 2-yl)phenol) characterized by an X-ray crystal-structure analysis. The oxidation occurs much faster when CuII is mixed with 1 in the presence of H2O2, with 80% hydroxylation observed within a few minutes. The mononuclear complex formed with 1-methyl-2-phenyl-1H-benzimidazole (3) shows no hydroxylation under these conditions. It is concluded that the hydroxylation requires the presence of a ligand capable of stabilizing a binuclear species, but no special coordinative activation of the copper is required.