900493-82-5

Basic information

• Product Name: allyl 1-(3-ethoxy-3-oxopropyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate
• Synonyms: allyl 1-(3-ethoxy-3-oxopropyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate
• CAS NO: 900493-82-5
• Molecular Weight: 388.485
• Mol File: 900493-82-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: allyl 1-(3-ethoxy-3-oxopropyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 1-(3-ethoxy-3-oxopropyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate(900493-82-5)
• EPA Substance Registry System: allyl 1-(3-ethoxy-3-oxopropyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate(900493-82-5)

Safety Data

• Hazardous Substances Data: 900493-82-5(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 504-02-9 1,3-cylohexanedione 
• 75717-39-4 3-(phenylsulfanyl)cyclohex-2-en-1-one 

Relevant articles and documents

Asymmetric allylic alkylation of cyclic vinylogous esters and thioesters by Pd-catalyzed decarboxylation of enol carbonate and β-ketoester substrates

(Chemical Equation Presented) Excellent yields and enantioselectivities were achieved for the palladium-catalyzed asymmetric allylic alkylation of vinylogous thioesters. The close-to-neutral reaction conditions ensure that this reaction can tolerate a wide range of functionalities. Furthermore, this approach provides a convenient protocol for the synthesis of synthetically important α,α- and γ,γ-di-substituted cycloalkenones.