901774-46-7

Basic information

• Product Name: keto rocaglate
• Synonyms: keto rocaglate
• CAS NO: 901774-46-7
• Molecular Weight: 490.51
• Mol File: 901774-46-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: keto rocaglate(CAS DataBase Reference)
• NIST Chemistry Reference: keto rocaglate(901774-46-7)
• EPA Substance Registry System: keto rocaglate(901774-46-7)

Safety Data

• Hazardous Substances Data: 901774-46-7(Hazardous Substances Data)

Downstream Products

• 959461-41-7 (3R,3aR,8bR)-8b-Hydroxy-6,8-dimethoxy-3a-(4-methoxy-phenyl)-3-phenyl-2,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-1-one 
• 901774-51-4 (3S,3aR,8bR)-8b-Hydroxy-6,8-dimethoxy-3a-(4-methoxyphenyl)-3-phenyl-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]benzofuran-1-one 
• 901774-43-4 exo methyl rocaglate 
• 143901-35-3 aglafoline 
• 190385-15-0 endo rocaglic acid 
• 84573-16-0 rocaglamide 
• 901774-52-5 exo rocaglic acid 

Relevant articles and documents

Enantioselective photocycloaddition mediated by chiral Bronsted acids: Asymmetric synthesis of the rocaglamides

Enantioselective syntheses of methyl rocaglate and the related natural products rocaglamide and rocaglaol are outlined. The approach involves enantioselective [3 + 2] photocycloaddition promoted by chiral Bronsted acids (TADDOLs) to afford an aglain precursor followed by a ketol shift/reduction sequence to the rocaglate core. Copyright