90192-98-6Relevant articles and documents
Hydroxyl-Assisted Carbonylation of Alkenyltin Derivatives: Development and Application to a Formal Synthesis of Tubelactomicin A
Sommer, Heiko,Fürstner, Alois
supporting information, p. 3210 - 3213 (2016/07/13)
Alkenyltin derivatives flanked by a hydroxyl group are subject to methoxycarbonylation when treated with catalytic amounts of Pd(OAc)2 and Ph3As in MeOH under a CO atmosphere; key to success is the use of 1,4-benzoquinone as a stoich
Stereodivergent total synthesis of (+)-aspergillide B and (+)-7-epi-aspergillide A
Sridhar,Srihari
, p. 578 - 587 (2013/02/26)
The stereoselective total syntheses of (+)-aspergillide B and (+)-7-epi-aspergillide A were achieved. The key reactions include Noyori's asymmetric transfer hydrogenation, an Achmatowicz rearrangement, a Ferrier-type alkynylation, a hydrosilylation-protodesilylation, a CBS (Corey-Bakshi-Shibata) oxazaborolidine reduction, a Yamaguchi macrolactonization, and a Mitsunobu macrolactonization. The stereoselective total syntheses of (+)-aspergillide B and (+)-7-epi-aspergillide A were achieved. The key reactions include Noyori's asymmetric transfer hydrogenation, an Achmatowicz rearrangement, a Ferrier-type alkynylation, a hydrosilylation-protodesilylation, a CBS (Corey-Bakshi-Shibata) oxazaborolidine reduction, a Yamaguchi macrolactonization, and a Mitsunobu macrolactonization. Copyright
Stereoconvergent synthesis of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A
Yadav,Raj Kumar,Sabitha
, p. 463 - 466 (2008/09/18)
Stereoconvergent syntheses of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A are reported.
