902137-36-4

Basic information

• Product Name: (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carboxylic acid ethyl ester
• Synonyms: (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carboxylic acid ethyl ester
• CAS NO: 902137-36-4
• Molecular Weight: 366.417
• Mol File: 902137-36-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carboxylic acid ethyl ester(902137-36-4)
• EPA Substance Registry System: (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carboxylic acid ethyl ester(902137-36-4)

Safety Data

• Hazardous Substances Data: 902137-36-4(Hazardous Substances Data)

Upstream product

• 902137-35-3 2-bromobenzaldehyde O-(phenylmethyl)oxime 
• 7149-65-7 ethyl (S)-pyroglutamate 
• 56-86-0 L-glutamic acid 
• 2687-43-6 O-benzylhydoxylamine hydrochloride 
• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 902137-39-7 (E)-3-{(S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidin-2-yl}-acrylic acid ethyl ester 
• 902137-38-6 (S)-1-[2-(Benzyloxyimino-methyl)-phenyl]-5-oxo-pyrrolidine-2-carbaldehyde 
• 902137-37-5 2-(2-hydroxymethyl-5-oxo-pyrrolidin-1-yl)-benzaldehyde O-benzyl-oxime 

Relevant articles and documents

An improved synthesis of (-)-martinellic acid via radical addition-cyclization-elimination reaction of chiral oxime ether

A concise formal synthesis of (-)-martinellic acid has been accomplished by preparing optically active dipyrroloquinoline as a key synthetic intermediate, which was prepared via the radical addition-cyclization-elimination of oxime ether carrying an unsaturated ester followed by two chemoselective reductions of the carbonyl groups. Georg Thieme Verlag Stuttgart.