90381-85-4

Basic information

• Product Name: (E)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate
• Synonyms: (E)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate
• CAS NO: 90381-85-4
• Molecular Weight: 286.779
• Mol File: 90381-85-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate(90381-85-4)
• EPA Substance Registry System: (E)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate(90381-85-4)

Safety Data

• Hazardous Substances Data: 90381-85-4(Hazardous Substances Data)

Upstream product

• 111220-84-9 (Z)-methyl 2-(p-chlorophenylsulphinyl)-4-methylpent-2-enoate 
• 102714-52-3 methyl 2-(p-chlorophenylsulphinyl)-4-methyl-3-piperidinopentanoate 
• 111220-81-6 methyl 2-(p-chlorophenylsulphinyl)-4-methyl-3-(4-methylpiperidino)pentanoate 
• 111220-80-5 methyl 2-(p-chlorophenylsulphinyl)-4-methyl-3-(2-methylpiperidino)pentanoate 
• 73281-90-0 methyl 4-chlorophenylsulfinylacetate 
• 78-84-2 isobutyraldehyde 
• 102714-49-8 methyl 2-(p-chlorophenylsulphinyl)-3-phenyl-3-pyrrolidinopropanoate 
• 102714-51-2 methyl 2-(p-chlorophenylsulphinyl)-3-(2-methylpiperidino)-3-phenylpropanoate 
• 111220-77-0 methyl 2-(p-chlorophenylsulphinyl)-3-(3-methylpiperidino)-3-phenylpropanoate 
• 102714-50-1 methyl 2-(p-chlorophenylsulphinyl)-3-phenyl-3-piperidinopropanoate 
• 111220-78-1 methyl 2-(p-chlorophenylsulphinyl)-3-hexanethyleneimino-3-phenylpropanoate 

Relevant articles and documents

Stereochemistry in the Knoevenagel Reaction of Methyl Arylsulphinylacetate and Aldehydes

The stereochemistry of the mechanism of the amine-catalyzed Knoevenagel reaction has been studied.Simple treatment of methyl arylsulphinylacetate (1) and aldehydes (2) with a catalytic amount of a secondary amine produced thermodynamically stable E-alkene

Selective Synthesis of α-Sulphenyl-, α-Sulphinyl-, and α-Sulphonyl-α,β-unsaturated Carbonyl Compounds by the Knoevenagel Reaction

Simple treatment of aldehydes with the carbonyl compounds (1) 2COCH2S(O)nAr; n = 0, 1, 2> and piperidine stereoselectively produces the condensation products (7), the stereochemistry of which is controlled by the steric requirements of two fu