90382-96-0

Basic information

• Product Name: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-methyl-hex-2-ynyl ester
• CAS NO: 90382-96-0
• Molecular Weight: 328.331
• Mol File: 90382-96-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-methyl-hex-2-ynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-methyl-hex-2-ynyl ester(90382-96-0)
• EPA Substance Registry System: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-methyl-hex-2-ynyl ester(90382-96-0)

Safety Data

• Hazardous Substances Data: 90382-96-0(Hazardous Substances Data)

Upstream product

• 26059-43-8 hept-3-yn-2-one 
• 627-19-0 1-Pentyne 
• 20445-31-2 R-(+)-α-trifluoromethyl-α-methoxy-phenylacetic acid 
• 90411-27-1 (R)-hept-3-yn-2-ol 

Relevant articles and documents

Cyclopentenone Derivatives, IX. - Enantioselective Routes to Brefeldin-A

By combining stereoselective Michael additions to substituted cyclopentenones with a stereospecific reduction of the C4 ketone, which is controlled by the C15 configuration, an enantioselective route to (-)-brefeldin-A is developed, starting with the easily available chiral carbinol 11.A second technique makes use of chirality transfer in Michael additions to chiral 4-acetoxy-2-cyclopenten-1-one.