90408-94-9

Basic information

• Product Name: 2,2,2-trichloroethyl 6β-methylallyl-6α-phenylselenopenicillanate
• CAS NO: 90408-94-9
• Molecular Weight: 541.785
• Mol File: 90408-94-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloroethyl 6β-methylallyl-6α-phenylselenopenicillanate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloroethyl 6β-methylallyl-6α-phenylselenopenicillanate(90408-94-9)
• EPA Substance Registry System: 2,2,2-trichloroethyl 6β-methylallyl-6α-phenylselenopenicillanate(90408-94-9)

Safety Data

• Hazardous Substances Data: 90408-94-9(Hazardous Substances Data)

Upstream product

• 59085-70-0 2-methyl-3-prop-2-enyl phenylselenide 
• 51056-24-7 (2S,5R)-6-Diazo-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2,2,2-trichloro-ethyl ester 

Downstream Products

• 90425-28-8 2,2,2-trichloroethyl 6β-(3-p-tolylthio-2-methylprop-1-enyl)penicillanate 
• 90425-29-9 6β-(3-p-tolylthio-2-methylprop-1-enyl)penicillanic acid 

Relevant articles and documents

Preparation and Properties of Substituted 6&β-Vinylpenicillanic Acids

Routes to the title compounds are described, either using the selective addition of thiols to the known 6-allylidenepenicillanic acids or by the conjugate addition of Grignard derivatives, derived from 6,6-dibromopenicillanates, to substituted acrylates and acrylamides, followed by stereoselective reduction of the remaining 6-bromo-group to produce the 6β-substituted penicillanates.The 6β-derivatives containing the acryloyl side-chain were relatively unstable and readily underwent intramolecular rearrangement to the corresponding thiazepinones.