90417-11-1Relevant articles and documents
PROCESS FOR PRODUCING 2-SUBSTITUTED PYRIDINE DERIVATIVE
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Page/Page column 13, (2008/06/13)
The present invention provides a method of producing a pyridine derivative having a substituent at the 2-position of a heterocyclic structure conveniently and with fine selectivity. The present invention relates to a production method of a pyridine derivative having a substituent at the 2-position of a heterocyclic structure, which is represented by the formula (III), which includes reacting a 2-sulfonylpyridine derivative of the formula (I) with an organometallic compound of the formula (II) and the like, and the like: wherein each symbol is as defined in the Description.
ADDITION OF 2-SILYLAZOLES TO HETEROARYL CATIONS. SYNTHESIS OF UNSYMMETRICAL AZADIARYLS
Dondoni, Alessandro,Dall'Occo, Tiziano,Galliani, Guido,Mastellari, Annarosa,Medici, Alessandro
, p. 3637 - 3640 (2007/10/02)
Thiazole, pyridine and some of their benzoderivatives react via their N-ethoxycarbonyl chlorides with 2-trimethylsilylthiazole (1a) and 4-methyl-2-trimethylsilyloxazole (1b) to give the corresponding adducts at Cα which by oxidative deacylation afford azadiaryls.