90433-71-9

Basic information

• Product Name: trans-2,6-dimethyl-1-(N-methylphenylsulfonimidoyl)-3,5-heptadien-2-ol
• CAS NO: 90433-71-9
• Molecular Weight: 293.43
• Mol File: 90433-71-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-2,6-dimethyl-1-(N-methylphenylsulfonimidoyl)-3,5-heptadien-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2,6-dimethyl-1-(N-methylphenylsulfonimidoyl)-3,5-heptadien-2-ol(90433-71-9)
• EPA Substance Registry System: trans-2,6-dimethyl-1-(N-methylphenylsulfonimidoyl)-3,5-heptadien-2-ol(90433-71-9)

Safety Data

• Hazardous Substances Data: 90433-71-9(Hazardous Substances Data)

Upstream product

• 16647-04-4 6-methyl-3,5-heptadien-2-one 
• 80482-67-3 (-)-(R)-N,S-dimethyl-S-phenylsulfoximine 
• 33993-53-2 N,S-dimethyl-S-phenylsulfoximine 

Relevant articles and documents

Synthesis and Absolute Configuration of (-)-Rothrockene, a Non-Head-To-Tail Monoterpene

The total synthesis of (-)-rothrockene, trans-1-(1-methylethenyl)-2-(2-methyl-1-propenyl)cyclopropane, and its enantiomer is described.Utilization of (-)-(R)-N,S-dimethyl-S-phenylsulfoximine in the synthesis allowed for resolution of a precursor, regio- and diastereoface selectivity in a Simmons-Smith cyclopropanation, determination of absolute configuration based on X-ray crystallography, and introduction of a side-chain double bond.The absolute configuration of the natural substance is shown to be 1R,2S.