90470-72-7

Basic information

• Product Name: Benzene, 1-(dimethoxymethyl)-3-methyl-
• CAS NO: 90470-72-7
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 90470-72-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(dimethoxymethyl)-3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(dimethoxymethyl)-3-methyl-(90470-72-7)
• EPA Substance Registry System: Benzene, 1-(dimethoxymethyl)-3-methyl-(90470-72-7)

Safety Data

• Hazardous Substances Data: 90470-72-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 108-38-3 m-xylene 
• 100-80-1 3-methylstyrene 
• 620-23-5 m-tolyl aldehyde 
• 149-73-5 trimethyl orthoformate 
• 587-04-2 m-Chlorobenzaldehyde 
• 3395-80-0 1,1-dimethoxy-1-(3-chlorophenyl)methane 
• 74-88-4 methyl iodide 

Downstream Products

• 15728-26-4 2-(3-methylbenzylidene)malononitrile 
• 147678-08-8 1-phenyl-1-(3-methylphenyl)methyl methyl ether 
• 620-23-5 m-tolyl aldehyde 
• 1435943-19-3 methyl 4-(3-methylphenyl)-5-cyano-2-hydroxy-6-phenyl-3,4-dihydro-2H-pyran-2-carboxylate 
• 1148004-81-2 (E)-methyl 2-oxo-4-(m-tolyl)but-3-enoate 
• 1374030-81-5 C₁₇H₁₆O 
• 1374030-62-2 C₁₇H₁₈O₂ 
• 90470-71-6 1-methoxy-1-(3-methylphenyl)acetonitrile 

Relevant articles and documents

MOF-808 as a recyclable catalyst for the photothermal acetalization of aromatic aldehydes

Metal-organic frameworks (MOFs) show promise for catalysis applications due to their porosity, high internal surface area, and structural adaptability. Typical acetylation reactions of aldehydes require elevated temperatures and excess alcohol to drive the reactions to completion. In this current work, MOF-808 is used as a heterogeneous catalyst for acetylation of aldehydes in methanol using a mild photothermal process. Optimized conditions gave 72% yield of 2-(dimethoxymethyl)naphthalene in the presence of 10 mol% MOF-808 at 45 °C using only a fluorescent lamp. MOF-808 can be recycled up to 5 times with no loss in catalytic activity. A proof-of-principle substrate scope demonstrates the potential utility for aromatic and aliphatic substrates.

Silver-Catalyzed Olefination of Acetals and Ketals with Diazoesters to β-Alkoxyacrylates

The first silver-catalyzed reaction of acetals or ketals with diazoesters leading to trisubstituted or tetrasubstituted β-alkoxyacrylates is now reported. A broad range of acetals and ketals bearing different substituents is compatible with this protocol and thus provides an attractive approach for the synthesis of complex β-alkoxyacrylates. The power of this method was further demonstrated by the successful synthesis of picoxystrobin, which is one of the most popular agricultural fungicides commercialized by Dupont.

House bulb light-induced photochemical acetalization of carbonyl compounds catalyzed by Eosin Y

We have systematically studied the reactions of acetalization and found that high reaction efficiency can be achieved using cheap and readily available organic Eosin Y as catalyst. The reaction proceeds smoothly under house bulbs and shows excellent functional group tolerance. The substrates of the reaction system are compatible with aromatic aldehydes, aliphatic aldehydes, aromatic ketones, and cyclic ketones with high yields.