90472-61-0

Basic information

• Product Name: Silane, (1-methyl-2-phenylethoxy)diphenyl-, (R)-
• CAS NO: 90472-61-0
• Molecular Formula: C21H22OSi
• Molecular Weight: 318.491
• Mol File: 90472-61-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, (1-methyl-2-phenylethoxy)diphenyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1-methyl-2-phenylethoxy)diphenyl-, (R)-(90472-61-0)
• EPA Substance Registry System: Silane, (1-methyl-2-phenylethoxy)diphenyl-, (R)-(90472-61-0)

Safety Data

• Hazardous Substances Data: 90472-61-0(Hazardous Substances Data)

Upstream product

• 775-12-2 diphenylsilane 
• 103-79-7 1-phenyl-acetone 

Downstream Products

• 1572-95-8 (R)-1-phenyl-propan-2-ol 

Relevant articles and documents

Asymmetric Catalyses, 14. Enantioselective Hydrosilylation of Prochiral Ketones with Rh- and Pt-Complexes of Optically Active N-Chelate Ligands

N-chelate ligands with a lateral chiral center, which derive from optically active primary amines, amino acids, and amino acid derivatives, catalyze in Rh and Pt complexes the enantioselective hydrosilylation of acetophenone, benzyl methyl ketone, and tert-butyl methyl ketone with diphenyl- and 1-naphthylphenylsilane.The ketones are transformed into the corresponding silyl ethers which on hydrolysis yield the alcohols 1-phenylethanol, 1-phenyl-2-propanol and 3,3-dimethyl-2-butanol. 37 N ligands 1 - 37 with 2 (I) and K (XX) as well as 21 isolated complexes II - XIX and XXI - XXIII are tested.The best optical inductions exceed considerably those which were obtained with optically active phosphane containing catalysts used up to now.