904848-89-1Relevant articles and documents
Isolation and syn elimination of a peterson adduct to obtain optically pure product in the diastereoselective synthesis of oxazolidinone-functionalized enecarbamates
Solomon, Marissa R.,Saito, Hideaki,Sivaguru,Jockusch, Steffen,Inoue, Yoshihisa,Adam, Waldemar,Turro, Nicholas J.
body text, p. 362 - 366 (2010/04/23)
The Peterson reaction of (4R)-N-(trimethylsilyl)methyl-4-alkyloxazolidin-2- one gives (E/Z)-(4R)-N-(2', 3'- diphenylbut-1'-enyl)-4-alkyloxazolidin-2-ones (enecarbamates) with increasing (Z)-selectivity and moderate-to-high diastereoselectivity in the indi
Highly diastereoselective dioxetane formation in the photooxygenation of enecarbamates with an oxazolidinone chiral auxiliary: Steric control in the [2 + 2] cycloaddition of singlet oxygen through conformational alignment
Adam, Waldemar,Bosio, Sara G.,Turro, Nicholas J.
, p. 8814 - 8815 (2007/10/03)
The photooxygenation of oxazolidinone-substituted enecarbamates leads to diastereomerically pure dioxetanes. The high diastereoselectivity is rationalized in terms of effective π-facial control achieved by shielding one side of the double bond with the ch