90606-74-9

Basic information

• Product Name: 1,3-Cyclohexadiene-1-carboxaldehyde, 3-bromo-4-(phenylthio)-
• CAS NO: 90606-74-9
• Molecular Formula: C13H11BrOS
• Molecular Weight: 295.2
• Mol File: 90606-74-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Cyclohexadiene-1-carboxaldehyde, 3-bromo-4-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Cyclohexadiene-1-carboxaldehyde, 3-bromo-4-(phenylthio)-(90606-74-9)
• EPA Substance Registry System: 1,3-Cyclohexadiene-1-carboxaldehyde, 3-bromo-4-(phenylthio)-(90606-74-9)

Safety Data

• Hazardous Substances Data: 90606-74-9(Hazardous Substances Data)

Upstream product

• 85972-16-3 (Z)-2-Bromo-1-chloro-3-(phenylthio)butadiene 
• 107-02-8 acrolein 

Downstream Products

• 1208-88-4 4-phenylsulfanyl-benzaldehyde 

Relevant articles and documents

Preparation and Diels-Alder Reactivity of Several New Chalcogen-Halogen Substituted Butadienes

Addition of halogens and pseudohalogens across one ?-bond of 1,4-dichlorobut-2-yne, followed by a 1,4-elimination, is an efficient synthesis of several new polysubstituted butadienes.If the product dienes have a sulfur or selenium substituent they are quite reactive, undergoing cycloaddition with the moderately reactive dienophile methyl vinyl ketone at 20 deg C in the presence of boron trifluoride etherate.The regiochemistry of the cycloadditions was elucidated, and the limitations of the methodology are discussed.