90624-27-4

Basic information

• Product Name: bis(μ-chloro)bis(η3-indenyl)dipalladium(II)
• Synonyms: bis(μ-chloro)bis(η3-indenyl)dipalladium(II)
• CAS NO: 90624-27-4
• Molecular Weight: 514.055
• Mol File: 90624-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(μ-chloro)bis(η3-indenyl)dipalladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(μ-chloro)bis(η3-indenyl)dipalladium(II)(90624-27-4)
• EPA Substance Registry System: bis(μ-chloro)bis(η3-indenyl)dipalladium(II)(90624-27-4)

Safety Data

• Hazardous Substances Data: 90624-27-4(Hazardous Substances Data)

Upstream product

• 18053-75-3 3-Trimethylsilylinden 

Downstream Products

• 95-13-6 1-indene 
• 890529-05-2 [(η1-indenyl)Pd(benzylamine)Cl] 
• 890529-13-2 (C₆H₅CH₂NH₂)(P(C₆H₅)3)PdCl₂ 
• 890529-11-0 [(η1-indenyl)Pd(PPh3)(benzylamine)Cl] 
• 890529-07-4 [(η1-indenyl)Pd(PCy3)(benzylamine)Cl] 
• 677029-42-4 [(η5-indenyl)Pd(II)(Cl)(PPh3)] 
• 677029-44-6 [(η5-indenyl)Pd(II)(Cl)(P(cyclohexyl)3)] 

Relevant articles and documents

New Routes to η1- and (η3?η 5)-Indenylpalladium Complexes: Synthesis, Characterization, and Reactivities

The dimer {(η8-Ind)Pd(μ-Cl)}2 (6) reacts with t-BuNC to give the dimeric species {(η 1-Ind)-(t-BuNC)Pd(μ-Cl)}2 (10), whereas reaction with PR 3 gives the complexes (η-Ind)Pd(PR3)Cl (R = Ph (4), Cy (7), Me (8), OMe (9)). Complexes 4 and (1-Me-Ind)Pd(PPh3)Cl (5) can also be prepared by reacting (PhCN)2PdCl2 with Lilnd and PPh3. The structural characterization of complexes 4-7, 9, and 10 by 1H and 13C NMR spectroscopy and single-crystal X-ray diffraction studies has allowed an analysis of the indenyl ligand's mode of coordination, both in the solid-state and in solution. Compounds 4, 6, and 7 react with PhSiH3 in the absence of cocatalysts, whereas reaction with ethylene requires the presence of excess MAO to give polyethylene.