90687-25-5

Basic information

• Product Name: 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester(9CI)
• Synonyms: 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester(9CI)
• CAS NO: 90687-25-5
• Molecular Formula: C8H10O4
• Molecular Weight: 0
• Product Categories: CYCLOPENTANE
• Mol File: 90687-25-5.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester(9CI)(90687-25-5)
• EPA Substance Registry System: 3-Oxatricyclo[2.2.1.02,6]heptane-1-carboxylicacid,5-hydroxy-,methylester(9CI)(90687-25-5)

Safety Data

• Hazardous Substances Data: 90687-25-5(Hazardous Substances Data)

Upstream product

• 81763-39-5 exo-2,3-epoxy-6-methoxycarbonyl-7-oxabicyclo<2.2.1>heptane 
• 17791-32-1 7-Oxabicyclo<2.2.1>hept-5-en-2-carbonsaeure-methylester 

Relevant articles and documents

BRIEF SYNTHESES OF (+/-)-METHYL SHIKIMATE, (+/-)-METHYL EPISHIKIMATE AND STRUCTURAL VARIANTS

Two brief syntheses of (+/-)-methyl shikimate are described in a strategy which offers potentially flexible access to a range of analogues.New intramolecular rearrangement reactions of epoxides derived from methyl 7-oxabicyclohept-3-ene 6-carboxylate and methyl bicyclohept-3-ene 6 carboxylate are described.

COMPLEMENTARY SHORT SYNTHESES OF (+/-)-METHYL SHIKIMATE

Two syntheses of (+/-)-methyl shikimate from the adduct of furan and methyl acrylate are described.One requires the regioselective hydroxylation of (+/-)-5β,6β-dihydroxy-O,O-isopropylidene-2-methoxycarbonylcyclohexa-1,3-diene and the other cis-dihydroxyla