90719-78-1

Basic information

• Product Name: 2,6-bis{[(pyrid-2-ylmethyl)(tosyl)amino]methyl}pyridine
• Synonyms: 2,6-bis{[(pyrid-2-ylmethyl)(tosyl)amino]methyl}pyridine
• CAS NO: 90719-78-1
• Molecular Weight: 627.788
• Mol File: 90719-78-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,6-bis{[(pyrid-2-ylmethyl)(tosyl)amino]methyl}pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-bis{[(pyrid-2-ylmethyl)(tosyl)amino]methyl}pyridine(90719-78-1)
• EPA Substance Registry System: 2,6-bis{[(pyrid-2-ylmethyl)(tosyl)amino]methyl}pyridine(90719-78-1)

Safety Data

• Hazardous Substances Data: 90719-78-1(Hazardous Substances Data)

Upstream product

• 7703-74-4 2,6-bis-(bromomethyl)pyridine 
• 75391-97-8 4-methyl-N-(pyridin-2-ylmethyl)benzenesulfonamide 
• 55422-79-2 2,6-bis(chloromethyl)pyridine hydrochloric acid 
• 1195-59-1 2.6-bis(hydroxymethyl)pyridine 

Relevant articles and documents

Ligand tuning of single-site manganese-based catalytic antioxidants with dual superoxide dismutase and catalase activity

A bio-inspired manganese(ii) complex with a linear pentadentate ligand framework containing soft sulfur donors and an alternating NSNSN binding motif displays excellent dual CAT/SOD-like antioxidant activity with high turnover efficiency and good operation stability in an aqueous environment. the Partner Organisations 2014.

Syntheses of zinc complexes with multidentate nitrogen ligands: New catalysts for aldol reactions

The ligands 2,6-bis{[(pyrid-2-ylmethyl)amino]methyl}-pyridine with an N5 pattern and (6-{[(pyrid-2-ylmethyl)amino]methyl}pyrid-2-yl)methanol with an N3O pattern were synthesized. ZnII complexes of the two ligands could be obtained, and the single-crystal X-ray structure of (2,6-bis{[(pyrid-2-ylmethyl)amino]methyl}pyridine)zinc chloride showed Zn coordination to all five nitrogen atoms. The strong complexation of 2,6-bis{[(pyrid-2-ylmethyl)-amino]methyl}pyridine and (6-{[(pyrid-2-ylmethyl)amino]-methyl}pyrid-2-yl)methanol with ZnII were demonstrated by 1H NMR spectroscopic studies and electrospray mass spectrometry. The coupling of 2-hydroxyacetophenone and benzaldehyde was studied in the presence of the prepared Zn complexes, and it was shown that the coupling product was obtained at room temperature in up to 60% yield with 7.5 mol% of the zinc catalyst. The present complexes mimic the active site of the zinc-dependent class II aldolases, where ZnII is coordinated to three nitrogen atoms. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.