90751-75-0

Basic information

• Product Name: Rh₂(O₂C(CH₂)2CH₃)3(bis(4,4'-(1-triazene-1,3-diyl)dibenzamidine))dirhodium(II)
• Synonyms: Rh₂(O₂C(CH₂)2CH₃)3(bis(4,4'-(1-triazene-1,3-diyl)dibenzamidine))dirhodium(II)
• CAS NO: 90751-75-0
• Molecular Weight: 747.418
• Mol File: 90751-75-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh₂(O₂C(CH₂)2CH₃)3(bis(4,4'-(1-triazene-1,3-diyl)dibenzamidine))dirhodium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: Rh₂(O₂C(CH₂)2CH₃)3(bis(4,4'-(1-triazene-1,3-diyl)dibenzamidine))dirhodium(II)(90751-75-0)
• EPA Substance Registry System: Rh₂(O₂C(CH₂)2CH₃)3(bis(4,4'-(1-triazene-1,3-diyl)dibenzamidine))dirhodium(II)(90751-75-0)

Safety Data

• Hazardous Substances Data: 90751-75-0(Hazardous Substances Data)

Upstream product

• 536-71-0 diminazene 

Relevant articles and documents

Rhodium carboxylate complexes of diphenyltriazene and Berenil, a substituted triazene and DNA-binding ligand. Crystal and molecular structure of tetrakis (μ-acetato )bis(diphenyltriazene)dirhodium(II)

The crystal and molecular structure of the neutral adduct of diphenyltriazene (dptH) with rhodium acetate, [Rh2(O2CCH3)4-(dptH)2], was determined. The title compound belongs to the triclinic space group P1 with a = 8.173 (1) ?, b = 8.923 (2) ?, c = 12.191 (1) ?, α = 91.95 (1)°, β = 101.77 (1)°, γ = 101.54 (1)°, V = 850.2 (4) ?3, dcalcd = 1.63 g/m3, Z = 1, and mol wt = 834.46. The structure was refined on 1978 observed reflections to R = 0.077. The structure contains linearly bound diphenyltriazene with Rh-N bond lengths of 2.301 (8) ? and N-N bond lengths of 1.27 (2) and 1.32 (2) ?, with an N-N-N angle of 114 (1)°. The planes of the phenyl rings in one diphenyltriazene ligand are puckered at a dihedral angle of 39.7°. The correlations between the structure and the IR spectra of this complex have been used to assign structures of complexes of rhodium carboxylates with Berenil, a DNA-binding ligand. In this latter case both linear and bridging examples have been identified.