90754-64-6Relevant articles and documents
Development of high-load, soluble oligomeric sulfonate esters via ROM polymerization: Application to the benzylation of amines
Zhang, Mianji,Moore, Joel D.,Flynn, Daniel L.,Hanson, Paul R.
, p. 2657 - 2660 (2004)
The development of high-load, soluble oligomeric sulfonate esters, generated via ROM polymerization, and their utility in the facile benzylation of an array of amines is reported. These polymeric sulfonate esters exist as free-flowing powders, are stable
Highly efficient amination in neat water of benzyl chlorides with dialkylformamides catalysed by N-heterocyclic carbene-palladium(II)-1- methylimidazole complex
Chen, Wen-Xin,Zhang, Cai-Yun,Lu, Jian-Mei
, p. 611 - 614 (2013/11/06)
Dialkylformamides are excellent N-sources in the amination of benzyl chlorides when catalysed by a NHC-Pd(II)-Im complex. In the presence of NaOH and the catalyst, variously substituted benzyl chlorides and five different dialkylformamides reacted smoothly to afford the corresponding N,N-dialkyl-benzylamines in good to almost quantitative yields in eco-friendly solvent water at 50 °C within 3 h.