908023-69-8

Basic information

• Product Name: N-(<3',3'-(2)H2>allyl)aniline
• Synonyms: N-(<3',3'-(2)H2>allyl)aniline
• CAS NO: 908023-69-8
• Molecular Weight: 135.177
• Mol File: 908023-69-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(<3',3'-(2)H2>allyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(<3',3'-(2)H2>allyl)aniline(908023-69-8)
• EPA Substance Registry System: N-(<3',3'-(2)H2>allyl)aniline(908023-69-8)

Safety Data

• Hazardous Substances Data: 908023-69-8(Hazardous Substances Data)

Upstream product

• 14465-74-8 N-phenyl-N-prop-2-ynylamine 
• 10475-51-1 1,1-dideuterio-2-propenol 
• 62-53-3 aniline 

Downstream Products

• 110596-32-2 2-(<1',1'-(2)H2>allyl)-N,N-dimethylaniline 

Relevant articles and documents

Synthesis of secondary amines by titanium-mediated transfer of alkenyl groups from alcohols

Reaction of Ti(NMe2)4 with allyl alcohols and primary amines leads to the selective formation of secondary allylic amines. The allyl transfer from the alcohol to the amine occurs with selective allylic transposition. Due to substituent effects in the reactions, we postulate that the reaction occurs through a [2 + 2]/retro-[2 + 2]-cycloaddition mechanism. It was also found that a similar reaction could be accomplished with homoallylic alcohol. In this case, the more complex mechanism leads to the formation of 1-aza-spiro[5.5]undecane. Possible pathways for the homoallylic transfer and cyclization are discussed. Copyright