90826-96-3

Basic information

• Product Name: Acetic acid, (cyanophenylphosphino)-, ethyl ester
• CAS NO: 90826-96-3
• Molecular Formula: C11H12NO2P
• Molecular Weight: 221.196
• Mol File: 90826-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, (cyanophenylphosphino)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, (cyanophenylphosphino)-, ethyl ester(90826-96-3)
• EPA Substance Registry System: Acetic acid, (cyanophenylphosphino)-, ethyl ester(90826-96-3)

Safety Data

• Hazardous Substances Data: 90826-96-3(Hazardous Substances Data)

Upstream product

• 2946-59-0 dicyano(phenyl)phosphine 
• 105-36-2 ethyl bromoacetate 
• 90826-86-1 Tetra-n-butylammonium-phenylcyanphosphid 

Relevant articles and documents

Degradation of (PhP)5 by Cyanide: Formation, Structure, and Reactions of the Phenyl Cyanophosphide Ion

Phenyl cyanophosphide PhPCN- is formed in the ractions of P(CN)2- with phenyllithium and of PhP(CN)2 with CN-, and it may be prepared by nucleophilic degradation of (PhP)5 with ammonium or phosphonium cyanides.With sulfur it yields phenyl cyanodithiophosphinates 4, by alkylation alkyl(phenyl)cyanophosphanes 6 and by hydrolysis of the latter alkyl(phenyl)phosphine oxides 7. - The molecular structure of PhPCN (3c) as determined by X-ray analysis shows an almost planar anion with 102 deg CPC angle.A long PC and short CN bond in the PCN group make PhPCN- appear as "cyanide complex of phenylphosphinidene".