909266-29-1

Basic information

• Product Name: 1-Azido-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3,5-dinitro-benzene
• Synonyms: 1-Azido-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3,5-dinitro-benzene
• CAS NO: 909266-29-1
• Molecular Weight: 341.283
• Mol File: 909266-29-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Azido-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3,5-dinitro-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Azido-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3,5-dinitro-benzene(909266-29-1)
• EPA Substance Registry System: 1-Azido-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3,5-dinitro-benzene(909266-29-1)

Safety Data

• Hazardous Substances Data: 909266-29-1(Hazardous Substances Data)

Upstream product

• 61599-69-7 2-[(E)-2-(4-methoxyphenyl)vinyl]-1,3,5-trinitrobenzene 
• 118-96-7 2,4,6-Trinitrotoluene 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 909266-32-6 6-(4-acetyl-5-methyl-1H-1,2,3-triazol-1-yl)-4'-methoxy-2,4-dinitrostilbene 
• 909266-35-9 6-(4-acetyl-5-methyl-1H-1,2,3-triazol-1-yl)-2-azido-4'-methoxy-4-nitrostilbene 

Relevant articles and documents

Synthesis of 2-aryl- and 2-hetaryl-4-6-dinitroindoles from 2,4,6- trinitrotoluene

A general preparative method for the synthesis of the previously unknown substituted indoles 2-aryl- and 2-hetaryl-4,6-dinitroindoles from 2,4,6- trinitrotoluene (TNT) has been elaborated. The presented procedure involves condensation of TNT with aromatic and heteroaromatic aldehydes to give the corresponding (E)-stilbenes 1(a-k) and their heterocyclic analogues followed by regiospecific nucleophilic susbtitution of the ortho-nitro group in 1(a-k) with the azido group under the action of NaN3. The thermolysis of the azides 2)a-k) leads to 2-aryl- or 2-hetaryl-4,6-dinitroindoles 3(a-k).