91019-17-9Relevant articles and documents
Tertiary Arsine Complexes of Copper and Zinc Group Metals with Coordinated Perchlorate
Naikar, S. B.,Nanje Gowda, N. M.,Reddy, G. K. N.
, p. 133 - 136 (2007/10/02)
A series of three- and four-coordinate perchlorate complexes of copper(I), silver(I), zinc(II) and cadmium(II) of the general compositions: ML2ClO4 (M = Cu, Ag; L = Cy3As; M = Ag; L = Nap2EtAs); M(Cy3As)2(ClO4)2 (M = Zn, Cd), ML3ClO4 (M = Cu, Ag; L = Ph2EtAs, Ph2PrnAs, o-tolyl3P; M = Ag; L = Nap2MeAs); and ML3(ClO4)2 (M = Zn, Cd; L = Ph2MeAs, Ph2EtAs, Ph2PrnAs) have been prepared and characterised by IR and PMR spectroscopy and conductivity measurements.IR spectral data suggest coordination of perchlorate in most of these complexes.The stereochemistry of the complexes depends on the size of the arsine ligands.