910650-09-8

Basic information

• Product Name: (C₆H₅)3PCH₃⁽¹⁺⁾*[Mo(NC₆H₃(CH(CH₃)2)2)(CC(CH₃)2C₆H₅)(OC(CF₃)2CH₃)2]^(1-)=C₁₉H₁₈P[Mo(NC₆H₃(C₃H₇)2)(CC₉H₁₁)(OC(CF₃)2CH₃)2]
• CAS NO: 910650-09-8
• Molecular Weight: 1041.85
• Mol File: 910650-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅)3PCH₃⁽¹⁺⁾*[Mo(NC₆H₃(CH(CH₃)2)2)(CC(CH₃)2C₆H₅)(OC(CF₃)2CH₃)2]^(1-)=C₁₉H₁₈P[Mo(NC₆H₃(C₃H₇)2)(CC₉H₁₁)(OC(CF₃)2CH₃)2](CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)3PCH₃⁽¹⁺⁾*[Mo(NC₆H₃(CH(CH₃)2)2)(CC(CH₃)2C₆H₅)(OC(CF₃)2CH₃)2]^(1-)=C₁₉H₁₈P[Mo(NC₆H₃(C₃H₇)2)(CC₉H₁₁)(OC(CF₃)2CH₃)2](910650-09-8)
• EPA Substance Registry System: (C₆H₅)3PCH₃⁽¹⁺⁾*[Mo(NC₆H₃(CH(CH₃)2)2)(CC(CH₃)2C₆H₅)(OC(CF₃)2CH₃)2]^(1-)=C₁₉H₁₈P[Mo(NC₆H₃(C₃H₇)2)(CC₉H₁₁)(OC(CF₃)2CH₃)2](910650-09-8)

Safety Data

• Hazardous Substances Data: 910650-09-8(Hazardous Substances Data)

Upstream product

• 139220-25-0 bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum 
• 19493-09-5 Methylenetriphenylphosphorane 

Relevant articles and documents

Reaction of phosphoranes with Mo(N-2,6-i-Pr2C6H 3) (CHCMe3)[OCMe(CF3)2]2: Synthesis and reactivity of an anionic imido alkylidyne complex

The reaction of Ph3P=CH2 with Mo(NAr)(CHCMe 3)[OCMe (CF3)2]2 (Ar = 2,6-i-Pr 2C6H3) produces the anionic alkylidyne complex {Ph3PMe}{Mo(NAr)(CCMe3)[OCMe(CF3) 2]2}. An X-ray structure determination of the complex reveals a bent Mo-N-C angle for the imido group, as expected when a metal-carbon triple bond is present. The anion has been shown to react with electrophiles predominantly at the imido nitrogen.