911291-36-6

Basic information

• Product Name: 3,4,6-tri-O-benzyl-β-D-mannopyranose
• Synonyms: 3,4,6-tri-O-benzyl-β-D-mannopyranose
• CAS NO: 911291-36-6
• Molecular Weight: 450.532
• Mol File: 911291-36-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3,4,6-tri-O-benzyl-β-D-mannopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6-tri-O-benzyl-β-D-mannopyranose(911291-36-6)
• EPA Substance Registry System: 3,4,6-tri-O-benzyl-β-D-mannopyranose(911291-36-6)

Safety Data

• Hazardous Substances Data: 911291-36-6(Hazardous Substances Data)

Upstream product

• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 127299-77-8 phenyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 29073-91-4 1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 100-39-0 benzyl bromide 

Downstream Products

• 225924-93-6 1,2-di-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranose 
• 225924-67-4 allyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-2-O-allyl-3,4-di-O-benzyl-α-D-mannopyranoside 
• 225924-68-5 allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside 
• 79218-68-1 ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 108869-64-3 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate 

Relevant articles and documents

Facile synthesis of sugar lactols via bromine-mediated oxidation of thioglycosides

Synthesis of a variety of sugar lactols (hemiacetals) has been accomplished in moderate to excellent yields by using bromine-mediated oxidation of thioglycosides. It was found that acetonitrile is the optimal solvent for this oxidation reaction. This approach involving bromine as oxidant is superior to that using N-bromosuccinimide (NBS) which produces byproduct succinimide often difficult to separate from the lactol products.

β-glycosides of hydroxyproline via an umpolung approach

Reaction of 1,2-O-dibutylstannylene-3,4-6-tri-O-benzyl-β-D- mannopyranose with Nα-fluorenylmethoxycarbonyl-cis-4- trifluoromethanesulfonyl-oxyproline allyl ester led to formation of a β-mannoside of trans-4-hydroxyproline. Subsequent manipulation of the C