91230-07-8

Basic information

• Product Name: benzyl (2-methylallyl)carbamate
• Synonyms: benzyl (2-methylallyl)carbamate
• CAS NO: 91230-07-8
• Molecular Weight: 205.257
• Mol File: 91230-07-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: benzyl (2-methylallyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (2-methylallyl)carbamate(91230-07-8)
• EPA Substance Registry System: benzyl (2-methylallyl)carbamate(91230-07-8)

Safety Data

• Hazardous Substances Data: 91230-07-8(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 2878-14-0 2-methylallylamin 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 621-84-1 O-benzyl carbamate 
• 59085-70-0 2-methyl-3-prop-2-enyl phenylselenide 

Downstream Products

• 1078123-39-3 benzyl N-[2-methyl-1-(2,4,6-trimethoxyphenyl)propyl]carbamate 

Relevant articles and documents

Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins

Intermolecular C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent 'ene'-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, α-chloroamide, and flavin hydroquinone. This unique mechanism ensures that radical formation only occurs when both substrates are present within the protein active site. This active site can control the radical terminating hydrogen atom transfer, enabling the synthesis of enantioenriched γ-stereogenic amides. This work highlights the potential for photoenzymatic catalysis to enable new biocatalytic transformations via previously unknown electron transfer mechanisms.

Relay catalysis by a metal-complex/bronsted acid binary system in a tandem isomerization/carbon-carbon bond forming sequence

A one-pot tandem isomerization/carbon-carbon bond forming sequence catalyzed by a ruthenium complex/Bronsted acid binary system is demonstrated. The method enables the use of readily available allylamides to deliver reactive imines under relay catalysis using a binary catalytic system. Subsequent Bronsted acid catalyzed carbon-carbon bond forming reactions of the generated imines with nucleophilic components afforded Friedel-Crafts and Mannich products in good yields. Copyright

Direct Conversion of Allylic Selenides to Protected Allylic Amines

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