91237-66-0

Basic information

• Product Name: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II)
• Synonyms: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II)
• CAS NO: 91237-66-0
• Molecular Formula: C72H48 N6 Ru
• Molecular Weight: 0
• Mol File: 91237-66-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 543.1°Cat760mmHg
• Flash Point: 242.1°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 2.63E-11mmHg at 25°C
• CAS DataBase Reference: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II)(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II)(91237-66-0)
• EPA Substance Registry System: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II)(91237-66-0)

Safety Data

• Hazardous Substances Data: 91237-66-0(Hazardous Substances Data)

Usage

InChI:InChI=1/3C24H16N2.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;/h3*1-16H;/q;;;+2

Relevant articles and documents

Enantiomeric Separations of Ruthenium (II) Polypyridyl Complexes Using HPLC With Cyclofructan Chiral Stationary Phases

The enantiomeric separation of 21 ruthenium (II) polypyridyl complexes was achieved with a novel class of cyclofructan-based chiral stationary phases (CSPs) in the polar organic mode. Aromatic derivatives on the chiral selectors proved to be essential for enantioselectivity. The R-napthylethyl carbamate functionalized cyclofructan 6 (LARIHC CF6-RN) column proved to be the most effective overall, while the dimethylphenyl carbamate cyclofructan 7 (LARIHC CF7-DMP) showed complementary selectivity. A combination of acid and base additives was necessary for optimal separations. The retention factor vs. acetonitrile/methanol ratio plot showed a U-shaped retention curve, indicating that different interactions take place at different polar organic solvent compositions. The separation results indicated that π-π interactions, steric effects, and hydrogen bonding contribute to the enantiomeric separation of ruthenium (II) polypyridyl complexes with cyclofructan chiral stationary phases in the polar organic mode.