91285-94-8

Basic information

• Product Name: O-benzyl S-(pyridin-2-yl)carbonothioate
• Synonyms: O-benzyl S-(pyridin-2-yl)carbonothioate
• CAS NO: 91285-94-8
• Molecular Weight: 245.302
• Mol File: 91285-94-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: O-benzyl S-(pyridin-2-yl)carbonothioate(CAS DataBase Reference)
• NIST Chemistry Reference: O-benzyl S-(pyridin-2-yl)carbonothioate(91285-94-8)
• EPA Substance Registry System: O-benzyl S-(pyridin-2-yl)carbonothioate(91285-94-8)

Safety Data

• Hazardous Substances Data: 91285-94-8(Hazardous Substances Data)

Upstream product

• 2637-34-5 pyridine-2-thione 
• 501-53-1 benzyl chloroformate 
• 2637-34-5 2-Sulfanylpyridine 

Downstream Products

• 1148-11-4 N-Benzyloxycarbonyl-L-proline 
• 6372-14-1 N-((benzyloxy)carbonyl)-L-phenylalaninol 
• 6216-65-5 N-benzyloxycarbonyl-L-valinol 
• 39896-97-4 benzyl-carbamic acid benzyl ester 
• 22733-94-4 benzyl cyclohexanecarboxylate 
• 59040-31-2 1,4-but-2-ynoic acid benzyl ester 
• 103-41-3 benzy cinnamate 
• 122-63-4 benzyl proprionate 
• 120-51-4 benzoic acid benzyl ester 
• 7432-21-5 N-carbobenzyloxy-L-tryptophane 
• 6968-11-2 N,N'-bis(benzyloxycarbonyl)-L-cystine 
• 1145-80-8 N-(benzyloxycarbonyl)-L-serine 
• 1149-26-4 (S)-N-(benzyloxycarbonyl)valine 
• 1142-20-7 N-Cbz-Ala 

Relevant articles and documents

Chelation-Based Homologation by Reaction of Organometallic Reagents with O -Alkyl S -Pyridin-2-yl Thiocarbonates: Synthesis of Esters from Grignard Reagents

The one-carbon homologative esterification of Grignard reagents with O- alkyl S -pyridin-2-yl thiocarbonates has been explored. This one-step synthesis of esters from Grignard reagents is the first case to involve chelation-stabilized intermediates.

New Amino-protective Reagents for t-Butoxycarbonylation and Benzyloxycarbonylation of Amines and Amino Acids

New amino-protective reagents for t-butoxycarbonylation and benzyloxycarbonylation of amines and amino acids have been developed. t-Butyl 2-pyridyl carbonate and t-butyl S-(2-pyridyl) thiocarbonate react cleanly with various amines and amino acids to afford N-Boc amines and N-Boc amino acids in high yields.Benzyl 2-pyridyl carbonate and O-benzyl S-(2-pyridyl) thiocarbonate are also found to be very effective in the benzyloxycarbonylation of amino acids.