91326-24-8Relevant articles and documents
SYNTHESIS OF ORGANOSULFONYLACETIC ACID
Mirskova, A.N.,Kryukova, Yu.I.,Levkovskaya, G.G.,Guseva, S.A.,Voronkov, M.G.
, p. 545 - 550 (2007/10/02)
Alkylsulfonylacetic acids and their esters were obtained by the alcoholysis of alkyl β,β-dichlorovinyl sulfones and the oxidation of alkylthioacetic acids.Arylsulfonylacetic acids were synthesized by the reaction of sodium arenesulfinates with monochloroacetic acid.The optimum conditions for the reaction were obtained.Arylsulfonylacetic esters were obtained by the reaction of monochloroacetic esters with sodium arenesulfinate in DMFA, and their hydrolysis led to the corresponding acids with yields of 65-98percent.Dichloroacetic estersreacts with arenesulfinates, forming di(arylsulfonyl)acetic esters.