913288-93-4

Basic information

• Product Name: (2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexanethioic acid S-{(1S,2R)-2-[benzyl-(2,4,6-trimethyl-benzenesulfonyl)-amino]-1-phenyl-propyl} ester
• Synonyms: (2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexanethioic acid S-{(1S,2R)-2-[benzyl-(2,4,6-trimethyl-benzenesulfonyl)-amino]-1-phenyl-propyl} ester
• CAS NO: 913288-93-4
• Molecular Weight: 696.103
• Mol File: 913288-93-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexanethioic acid S-{(1S,2R)-2-[benzyl-(2,4,6-trimethyl-benzenesulfonyl)-amino]-1-phenyl-propyl} ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexanethioic acid S-{(1S,2R)-2-[benzyl-(2,4,6-trimethyl-benzenesulfonyl)-amino]-1-phenyl-propyl} ester(913288-93-4)
• EPA Substance Registry System: (2S,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexanethioic acid S-{(1S,2R)-2-[benzyl-(2,4,6-trimethyl-benzenesulfonyl)-amino]-1-phenyl-propyl} ester(913288-93-4)

Safety Data

• Hazardous Substances Data: 913288-93-4(Hazardous Substances Data)

Upstream product

• 773-64-8 2-mesitylenesulphonyl chloride 
• 187324-62-5 (1S,2R)-2-(N-mesitylenesulfonylamino)-1-phenylpropan-1-ol 
• 37577-28-9 (1S,2R)-(+)-norphedrine 
• 913288-77-4 (1'S,2'R)-2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl thiolbenzoate 
• 913288-78-5 (1'S,2'R)-2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl thiolpropionate 
• 913288-76-3 (1'S,2'R)-2'-(N-mesitylenesulfonylamino)-1'-phenylpropyl thiolbenzoate 
• 913288-73-0 (1S,2R)-2-(N-benzyl-N-mesitylenesulfonylamino)-1-phenylpropane-1-thiol 
• 913288-74-1 (1S,2R)-2-(N-mesitylenesulfonylamino)-1-phenyl-1-chloropropane 
• 913288-75-2 (2R,3R)-2-methyl-3-phenyl-1-(N-mesitylenesulfonylamino)-aziridine 

Relevant articles and documents

Achieving high selectivity and facile displacement with a new thiol auxiliary for boron-mediated aldol reactions

(Chemical Equation Presented) Synthesis of a new thiol auxiliary (1) is readily achieved (in five or six steps, >74% overall yield from norephedrine) and is shown to give high diastereoselectivity in boron-mediated anti-aldol reactions with a range of aldehydes. This new thiol auxiliary may be directly displaced by a range of nucleophiles under very mild conditions, to give the corresponding phosphonate esters, alcohols, acids, SNAC thiolesters, and methyl esters.