914646-14-3

Basic information

• Product Name: (S)-1-(4-nitrophenyl)allyl carbamate
• Synonyms: (S)-1-(4-nitrophenyl)allyl carbamate
• CAS NO: 914646-14-3
• Molecular Weight: 222.2
• Mol File: 914646-14-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-(4-nitrophenyl)allyl carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(4-nitrophenyl)allyl carbamate(914646-14-3)
• EPA Substance Registry System: (S)-1-(4-nitrophenyl)allyl carbamate(914646-14-3)

Safety Data

• Hazardous Substances Data: 914646-14-3(Hazardous Substances Data)

Upstream product

• 3019-71-4 Trichloroacetyl isocyanate 
• 914646-11-0 (S)-1-(4-nitrophenyl)-2-propen-1-ol 
• 555-16-8 4-nitrobenzaldehdye 
• 123232-63-3 1-(4-nitrophenyl)-prop-2-en-1-ol 

Downstream Products

• 56-75-7 chloramphenicol 
• 294637-52-8 (4R,5R)-5-(4-nitrophenyl)-4-hydroxymethyl-1,3-oxazolidin-2-one 

Relevant articles and documents

A short enantioselective synthesis of (-)-chloramphenicol and (+)-thiamphenicol using tethered aminohydroxylation

An efficient enantioselective synthesis of (-)-chloramphenicol (1) and (+)-thiamphenicol (2) is described. These antibiotics have been synthesized from commercially available 4-nitrobenzaldehyde and 4-(methylthio)benzaldehyde, respectively, using tethered aminohydroxylation and Sharpless asymmetric epoxidation as the chirality inducing steps.