91540-30-6

Basic information

• Product Name: 1-(prop-2-en-1-yl)-1a,9b-dihydro-1H-phenanthro[9,10-b]azirene
• CAS NO: 91540-30-6
• Molecular Formula: C₁₇H₁₅N
• Molecular Weight: 233.3077
• Mol File: 91540-30-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 346.8°C at 760 mmHg
• Flash Point: 148°C
• Density: 1.137g/cm³
• Vapor Pressure: 5.63E-05mmHg at 25°C
• Refractive Index: 1.638
• CAS DataBase Reference: 1-(prop-2-en-1-yl)-1a,9b-dihydro-1H-phenanthro[9,10-b]azirene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(prop-2-en-1-yl)-1a,9b-dihydro-1H-phenanthro[9,10-b]azirene(91540-30-6)
• EPA Substance Registry System: 1-(prop-2-en-1-yl)-1a,9b-dihydro-1H-phenanthro[9,10-b]azirene(91540-30-6)

Safety Data

• Hazardous Substances Data: 91540-30-6(Hazardous Substances Data)

Upstream product

• 67464-46-4 1a,9b-dihydro-1H-phenanthro<9,10-b>azirine 
• 107-05-1 3-chloroprop-1-ene 
• 53581-32-1 (+/-)-trans-9-Azido-10-hydroxy-9,10-dihydrophenanthrene 
• 74684-57-4 1a,9b-dihydro-1H-phenanthro<9,10-b>azirine 
• 91540-31-7 trans-9,10-dihydro-10<(tributylphospho)azido>phenanthren-9-ol 

Relevant articles and documents

The Chemistry of Polycyclic Arene Imine. VI. 1--1a,9b-dihydrophenanthroazirine an Unusual Allylation Product of Phenanthrene 9,10-Imine

Phenanthrene 9,10-imine (1) was shown to react with allyl bromide and 50percent aqueous sodium hydroxide under phase transfer catalysis conditions to give the title compound 3 as the only product.The starting imine 1 is assumed to undergo initially bis alkylation to form an N,N-di-(2-propenyl)phenanthrene 9,10-iminium salt (4) which, in turn, is attacked by a deprotonated phenanthrene imine anion (5).The structure of 3 has been determined by a single crystal X-ray diffraction analysis.

The Chemistry of Polycyclic Arene Imines. V. Reactions of Phenanthrene 9,10-Imine with Nucleophiles under Phase Transfer Conditions

Reactions of phenanthrene 9,10-imine (1) with alkyl halides, sodium azide and ammonium thiocyanate in two liquid phase systems were investigated.In the presence of aqueous sodium hydroxide and alkyl halides triethylbenzylammonium (TEBA) salts promote N-al