91549-28-9Relevant articles and documents
Facile Thermal ?2 + ?2> Cycloadditions of Some Cyclopropanes with TCNE. A Remarkable Effect of the Fluorene Unit Fused in a Spiro Fashion
Nishida, Shinya,Murakami, Masashi,Mizuno, Tetsuo,Tsuji, Takashi,Oda, Hirofumi,Shimizu, Nobujiro
, p. 3428 - 3429 (1984)
The fact that 1a, as well as similarly spiroactivated 1b and 5, readily reacted with TCNE to afford a ?2 + ?2> cycloadduct, whereas 3 was practically unreactive, suggests an initial electron transfer in the cycloaddition.