91638-51-6Relevant articles and documents
Amino acid-catalyzed asymmetric α-amination of carbonyls
Thomassigny, Christine,Prim, Damien,Greck, Christine
, p. 1117 - 1119 (2006)
Electrophilic amination of ketones and aldehydes in the presence of dibenzylazodicarboxylate in dichloromethane, using L-azetidine carboxylic acid as a catalyst, is described. Yields and ee are discussed in comparison with the corresponding L-proline-cata
Enantioselective organocatalysis in ionic liquids: Addition of aliphatic aldehydes and ketones to diethyl azodicarboxylate
Kotrusz, Peter,Alemayehu, Sara,Toma, Stefan,Schmalz, Hans-Guenther,Adler, Andreas
, p. 4904 - 4911 (2007/10/03)
The enantioselective addition of aldehydes to diethyl azodicarboxylate in ionic liquids in the presence of chiral organocatalysts has been investigated. Of seven different organocatalysts tested, L-proline and L-thiazoline-2- carboxylic acid gave the high