916596-72-0

Basic information

• Product Name: (2S,3S,4R)-1-O-tert-butyldiphenylsilyl-2-octadecanoylamino-octadecane
• Synonyms: (2S,3S,4R)-1-O-tert-butyldiphenylsilyl-2-octadecanoylamino-octadecane
• CAS NO: 916596-72-0
• Molecular Weight: 822.384
• Mol File: 916596-72-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S,4R)-1-O-tert-butyldiphenylsilyl-2-octadecanoylamino-octadecane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4R)-1-O-tert-butyldiphenylsilyl-2-octadecanoylamino-octadecane(916596-72-0)
• EPA Substance Registry System: (2S,3S,4R)-1-O-tert-butyldiphenylsilyl-2-octadecanoylamino-octadecane(916596-72-0)

Safety Data

• Hazardous Substances Data: 916596-72-0(Hazardous Substances Data)

Upstream product

• 57-11-4 stearic acid 
• 554-62-1 D-ribo-phytosphingosine 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 34354-88-6 (2S,3S,4R)-2-(N-stearoylamino)octadecane-1,3,4-triol 

Downstream Products

• 1046791-17-6 (2S,3S,4R)-3-O-acetyl-1-O-tert-butyldiphenylsilyl-4-O-succinoyl-2-octadecanoylamino-octadecane 
• 1092062-69-5 C₆₀H₉₉NO₁₀Si 

Relevant articles and documents

Synthesis of a GM3 ganglioside analogue carrying a phytoceramide moiety by intramolecular glycosylation as a key step

A novel analogue of ganglioside GM3, in which sphingosine was replaced with a phytosphingosine moiety, was synthesized by intramolecular glycosylation as a key step. Glucose, a reducing terminal of the saccharide, and phytoceramide were first tethered by succinic acid and the derivative used for the subsequent glycosidic bond formation. The obtained glycosyl phytoceramide was further glycosylated with the sialyl galactose residue to afford a fully protected GM3 derivative, which was converted into the desired, final compound by using conventional deprotection procedures.