917114-13-7

Basic information

• Product Name: 2-(4-(tert-butyl)phenyl)quinoline
• Synonyms: 2-(4-(tert-butyl)phenyl)quinoline
• CAS NO: 917114-13-7
• Molecular Weight: 261.367
• Mol File: 917114-13-7.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 2-(4-(tert-butyl)phenyl)quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-(tert-butyl)phenyl)quinoline(917114-13-7)
• EPA Substance Registry System: 2-(4-(tert-butyl)phenyl)quinoline(917114-13-7)

Safety Data

• Hazardous Substances Data: 917114-13-7(Hazardous Substances Data)

Upstream product

• 772-38-3 4-tert-Butylphenylacetylene 
• 529-23-7 o-aminobenzaldehyde 
• 943-27-1 4'-t-butylacetophenone 
• 4403-69-4 2-amino-1-benzylamine 
• 612-62-4 2-Chloroquinoline 
• 123324-71-0 p-tert-butylphenylboronic acid 
• 2005-43-8 2-bromoquinoline 
• 27798-45-4 1-allyl-4-(tert-butyl)benzene 
• 62-53-3 aniline 
• 1210859-30-5 C₁₈H₂₁NO₂ 
• 15727-49-8 N-Phenylalanin 
• 67-68-5 dimethyl sulfoxide 
• 91-22-5 quinoline 
• 58106-57-3 (E)-3-(2-aminobenzene)acrylonitrile 

Downstream Products

• 1416892-63-1 (R)-2-(4-(tert-butyl)phenyl)-1,2,3,4-tetrahydroquinoline 
• 863487-45-0 2-(4-(tert-butyl)phenyl)-4-methylquinoline 
• 1127561-45-8 2-(4-(tert-butyl)phenyl)quinoline N-oxide 

Relevant articles and documents

Kinetic Resolution of 2,2-Disubstituted Dihydroquinolines through Chiral Phosphoric Acid-Catalyzed C6-Selective Asymmetric Halogenations

A novel kinetic resolution of 2,2-disubstituted dihydroquinolines was achieved by regioselective asymmetric halogenations enabled by chiral phosphoric acid catalysis. A series of dihydroquinolines bearing 2,2-disubstitutions were well-tolerated in these reactions, generating both the recovered dihydroquinolines and C-6-brominated products with high enantioselectivities, with s-factors up to 149. In addition, this kinetic resolution protocol is also applicable for 2,2-disubstituted tetrahydroquinoline and asymmetric iodonation reaction.

The preparation of a Co@C3N4catalyst and applications in the synthesis of quinolines from 2-aminobenzyl alcohols with ketones

An unsymmetrical diphenylphosphino-pyridinyl-triazole ligand was synthesized and characterized through IR, NMR and MS and the corresponding earth-abundant metal complex (cobalt) was prepared. Considering energy consumption and environmental friendliness, it is necessary to turn this diphenylphosphino-pyridinyl-triazole cobalt complex into a recyclable catalyst, which could easily be reused. Therefore, a heterogeneous catalyst was synthesized through Co-doping of C3N4, and the Co-nanoparticles on C3N4revealed high catalytic activity for the synthesis of quinolines with good recovery performance.

Enantioselective Synthesis of Tetrahydroquinolines via One-Pot Cascade Biomimetic Reduction?

A novel and efficient protocol for the synthesis of chiral tetrahydroquinoline derivatives with excellent enantioselectivities and high yields has been developed through one-pot cascade biomimetic reduction. The detailed reaction pathway includes the acid-catalyzed and ruthenium-catalyzed formation of aromatic quinoline intermediates and biomimetic asymmetric reduction.