917611-93-9

Basic information

• Product Name: (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate
• Synonyms: (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate
• CAS NO: 917611-93-9
• Molecular Weight: 572.797
• Mol File: 917611-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate(917611-93-9)
• EPA Substance Registry System: (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate(917611-93-9)

Safety Data

• Hazardous Substances Data: 917611-93-9(Hazardous Substances Data)

Upstream product

• 73537-22-1 (2E,6E)-3,7-dimethyl-10-oxodeca-2,6-dien-1-yl acetate 
• 917611-79-1 (2E,6E)-10-hydroxy-3,7-dimethyldeca-2,6-dienyl acetate 
• 106-28-5 Farnesol 
• 5233-99-8 10,11-epoxyfarnesol 
• 50502-44-8 10,11-epoxyfarnesyl acetate 
• 917611-87-1 (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dien-1-ol 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 917612-07-8 (4E,8E)-4,8-dimethyl-11-p-tolylundeca-4,8-dien-1-ol 
• 917612-09-0 (4E,8E)-4,8-dimethyl-11-m-tolylundeca-4,8-dien-1-ol 
• 917612-26-1 (5E,9E)-5,9-dimethyl-12-m-tolyldodeca-5,9-dienenitrile 
• 917612-24-9 (5E,9E)-5,9-dimethyl-12-p-tolyldodeca-5,9-dienenitrile 
• 917612-36-3 (6E,10E)-6,10-dimethyl-13-p-tolyltrideca-6,10-dien-2-one 
• 917612-37-4 (6E,10E)-6,10-dimethyl-13-m-tolyltrideca-6,10-dien-2-one 

Relevant articles and documents

Catalytic diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups

Highly diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups was catalyzed by tin(IV) chloride (10 mol %). The cyclizations of tert-butyldiphenylsilyl and triisopropylsilyl polyenol ethers gave 4α(equatorial)- and 4β(axial)-siloxypolycycles as major isomers, respectively. The strong nucleophilicity of pro-C(9), a (6E) geometry, and a bulky silyl group effectively favored the 4α-preference, whereas the weak nucleophilicity of pro-C(9), a (6Z)-geometry, and less steric hindrance of a silyl group favored the 4β-preference.